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1、武漢理工大學(xué)碩士學(xué)位論文凝膠注模成型制備βTCP多孔生物陶瓷的研究姓名:成國(guó)煌申請(qǐng)學(xué)位級(jí)別:碩士專業(yè):材料學(xué)指導(dǎo)教師:陳曉明20040501亟堡堡三盔堂堡圭堂垡墮皇AbstractCalciumphosphateceramicsarewidelyusedasbonereplacementsinthefieldoforalandorthopaedicsurgeryAsakindofmaterialhavingexcellentphysic

2、alchemistryperformance,theporous13tricalciumphosphate(13TCP)ceramichasgoodbiocompafibilityandbiodegradablecapabilityThismaterialcarlinduceproductionofnewbonemadplayanimportantroleofosteophonytorepairbonedefectshenceitiSa

3、nldealbonetransplantingmatedalHoweverthepresentpreparingmethodsoftheporous13一TCPbioceramicshavemanydisadvantagesGelcastingiSanovelmethodofformingceramicsandhasbeenincreasinglyemployedinpreparingcomplex—shaped,nearnetshap

4、eadvancedmaterialsInordertogetamoreeffectivepreparingtechnologyofporousceramics,porous13一TCPceramicswasfabricatedbyincorporationofformingporeagentsmethodandgelcastingmethodinthepaperFortheoptimalquanti諺ofgelfactors,throu

5、ghcarefulcomparingwiththetimeofforminggelandthestrengthofthegreengelbodywegotasfollowproportion:AMwas59,MBAMWas039,thedistilledwaterwas25m1initiatorWhichconcentrationwas15wt%was06ml,catalystwhichconcentrationwas1wt%was08

6、ml,thetemperaturewas50℃Inthisproportion,thetimeofforminggelwasfrom8to10minutesThecompressivestrengthofthegreengelbodieswasabout5000Pathedryshrinkageratewasabout50%andthegreenbodiesdidn’tfracturedInthePaperpreparationofac

7、oncentratedsuspensionwith10WviscosityandhighsolidvolumecontentandstabilityisthekeytosuccessingeleastingtechnologyTheresultsoftheexperimentindicatedthattheparticlesof13TCP/BGceramicshadperfectdispersingperformancewhenpHva

8、luewas10andthedispersantwasaddedWestudiedtherheologyofsuspensionof13TCP/BGceramicpowderwithlowviscosityandhighsolidcontentWjfoundthatthefactorsofquantityofthedispersant,pHvalueofthesolution,thecontentofthemonomerandtheGR

9、OSS—tinkingmonomeraddedinBG,themillingtimes,thesolidvolumecontentetcplayedanimportantroletoviscosityofthesuspensionIntheend,thesuspensionwithsolidvolumeloading58vol%wassuitableforneedofgelcastingtechnologyTheresearchresu

10、ltsindicatedthatthedryshrinkageof13TCP/BGgreenbodywasinverseproportionwithsolidvolumeloadingofthesuspensionAndtheformingporeagentshadinfluenceOnthedryshrinkageandthesinteringshrinkageBymeanofanalysisoftheTGDSCof13一TCP,BG

11、greenbodytheappropriatesinteringtedmologycouldbefixedon,ItwasanimportantdirectivesignificationtoimprovefinishedproductrateThroughanalysistheappearanceoftheporousceramicsbySEM,wemadesurethattheporous13一TCP/BGceramicshadgo

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